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It was in Mark Miller's Marvel Knights Spider Man series like 10 years ago...not sure if it has been brought up since then.

I think Blizzard is perhaps the best candidate. Even in his guest appearance on Agents of S.H.I.E.L.D., his big motivation for going through his plan that episode was his male friend/ possible crush,...

Guardians of the Sub-Dimensions or New Defenders (for a snappier title)

Magik
Valkyrie
Danielle Moonstar
Hellcat
Son of Satan
Cullen Bloodstone

They defend the various, more hellish...